Synthesis of chiral thiazoline ligands tethered to a sulfur function and first immobilization of a thiazoline-ligand

✍ Scribed by Isabelle Abrunhosa-Thomas; Alexander Betz; Mickael Denancé; Isabelle Dez; Annie-Claude Gaumont; Mihaela Gulea

• Publisher: John Wiley and Sons
• Year: 2010
• Tongue: English
• Weight: 304 KB
• Volume: 21
• Category: Article
• ISSN: 1042-7163
• DOI: 10.1002/hc.20603

✦ Synopsis

Abstract

A new family of thiazoline ligands tethered to a sulfanyl or a sulfinyl group has been prepared using short and efficient reaction sequences. Among the different structures, one sulfanyl‐thiazoline homopolymer was synthesized as a first example of an immobilized thiazoline ligand. The catalytic properties of these new ligands were evaluated in the Pd‐catalyzed allylic substitution. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:242–249, 2010; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20603