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t-BuOK-Mediated Hydrophosphination of Functionalized Alkenes: A Novel Synthesis of Chiral P,N- and P,P-Ligands.

✍ Scribed by Tanasri Bunlaksananusorn; Paul Knochel


Publisher
John Wiley and Sons
Year
2004
Weight
35 KB
Volume
35
Category
Article
ISSN
0931-7597

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The synthesis of P,P'-dimesityl-P,P'-diphenyldiphosphine and benzylmesitylphenylphosphine is described as well as the resolution of the latter ligand by means of homochiral organometallic complexes. The absolute configuration of the phosphine is assigned by NMR spectra, using the homochiral palladac