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Synthesis of New Chiral Bidentate (Phosphinophenyl)benzoxazine P,N-Ligands

✍ Scribed by E. Peter Kündig; Peter Meier


Publisher
John Wiley and Sons
Year
1999
Tongue
German
Weight
147 KB
Volume
82
Category
Article
ISSN
0018-019X

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The synthesis of P,P'-dimesityl-P,P'-diphenyldiphosphine and benzylmesitylphenylphosphine is described as well as the resolution of the latter ligand by means of homochiral organometallic complexes. The absolute configuration of the phosphine is assigned by NMR spectra, using the homochiral palladac