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Synthesis of chiral 1′-substituted oxazolinylferrocenes as chiral ligands for Pd-catalyzed allylic substitution reactions

✍ Scribed by Jaiwook Park; Zhenyu Quan; Sunwoo Lee; Kyo Han Ahn; Chang-Woo Cho


Book ID
108354783
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
143 KB
Volume
584
Category
Article
ISSN
0022-328X

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New chiral phosphinooxathiane ligands fo
✍ Hiroto Nakano; Yuko Okuyama; Hiroshi Hongo * 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 178 KB

New chiral ligands, phosphinooxathianes 3 and 6, were synthesized easily and their ability as ligands were examined in Pd-catalyzed asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate with dimethyl malonate to give an allylation product. Enantiomeric excess of up to 94% has been obtaine