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Synthesis of cationic poly-1,3-pentadiene under the action of Gustavson complex

✍ Scribed by V. A. Rozentsvet; V. G. Kozlov; N. A. Korovina; V. P. Ivanova

Book ID
111463750
Publisher
SP MAIK Nauka/Interperiodica
Year
2011
Tongue
English
Weight
171 KB
Volume
84
Category
Article
ISSN
1070-4272

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## Abstract 3‐Methyl‐1,3‐pentadiene has been polymerized with the Al(C~2~H~5~)~2~Cl/Nd(OCOC~7~H~15~)~3~/Al[CH~2~CH(CH~3~)~2~]~3~ system to crystalline polymers consisting essentially of cis‐1,4 units (β‰₯80%). NMR examination has shown that the polymers have an isotactic structure. This conclusion wa