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Synthesis of carbamates from aliphatic amines and dimethyl carbonate catalyzed by acid functional ionic liquids

โœ Scribed by Hancheng Zhou; Feng Shi; Xiong Tian; Qinghua Zhang; Youquan Deng


Book ID
108212884
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
204 KB
Volume
271
Category
Article
ISSN
1381-1169

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The syntheses of carbamates from reactio
โœ Tianlong Sima; Shu Guo; Feng Shi; Youquan Deng ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 91 KB

At 170ยฐC and using ionic liquids as solvent and catalyst, primary and secondary aliphatic amines could react with dimethyl carbonate to give alkyl carbamates with good yield. Due to its insolubility, the desired carbamate solid could be recovered by simple filtration from the two-layer mixture of di