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Synthesis of Methyl Carbamates from Primary Aliphatic Amines and Dimethyl Carbonate in Supercritical CO 2 : Effects of Pressure and Cosolvents and Chemoselectivity

✍ Scribed by Selva, Maurizio; Tundo, Pietro; Perosa, Alvise; Dall'Acqua, Federico


Book ID
127180269
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
278 KB
Volume
70
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES


The synthesis of alkyl carbamates from p
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At 130Β°C and in the presence of compressed CO 2 , primary aliphatic amines [RNH 2 , R=C 10 H 21 , C 8 H 17 , cHex, 1-(C 10 H 7 )CH 2 ] react with organic carbonates (R%OCO 2 R%; R%=Me, Et) to give alkyl carbamates (RNHCO 2 R%, 1). Although CO 2 promotes the reaction also at a low pressure, good yiel

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