At 130Β°C and in the presence of compressed CO 2 , primary aliphatic amines [RNH 2 , R=C 10 H 21 , C 8 H 17 , cHex, 1-(C 10 H 7 )CH 2 ] react with organic carbonates (R%OCO 2 R%; R%=Me, Et) to give alkyl carbamates (RNHCO 2 R%, 1). Although CO 2 promotes the reaction also at a low pressure, good yiel
β¦ LIBER β¦
Synthesis of Methyl Carbamates from Primary Aliphatic Amines and Dimethyl Carbonate in Supercritical CO 2 : Effects of Pressure and Cosolvents and Chemoselectivity
β Scribed by Selva, Maurizio; Tundo, Pietro; Perosa, Alvise; Dall'Acqua, Federico
- Book ID
- 127180269
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 278 KB
- Volume
- 70
- Category
- Article
- ISSN
- 0022-3263
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