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Synthesis of C 2 -Symmetric Chiral Amino Alcohols: Their Usage as Organocatalysts for Enantioselective Opening of Epoxide Ring

✍ Scribed by Turgut, Yilmaz; Aral, Tarik; Karakaplan, Mehmet; Deniz, Pinar; Hosgoren, Halil

Book ID: 120311974
Publisher: Taylor and Francis Group
Year: 2010
Tongue: English
Weight: 388 KB
Volume: 40
Category: Article
ISSN: 0039-7911
DOI: 10.1080/00397910903419878

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The C 2 -symmetrical bis-b-amino alcohols 1-6 were prepared and especially attention is focused on bridges, which link the two b-amino alcohol units. These ligands have been applied as chiral catalysts in the asymmetric addition of diethylzinc to aldehydes. sec-Alcohols have been obtained in good yi