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Synthesis of brominated allenic, 1-3-butadienyl, and cyclobutenyl diphenylphosphine oxides

โœ Scribed by Bogachenkov, A. S.; Ionin, B. I.


Book ID
118725652
Publisher
Springer
Year
2012
Tongue
English
Weight
150 KB
Volume
82
Category
Article
ISSN
1070-3632

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A simple synthesis of 1-(1,3-butadienyl)
โœ Paul F. De Cusati; R.A. Olofson ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 293 KB

Crotonaldehyde and its congeners are conveniently and often stereospecifically converted to trans-1 -(l ,Sbutadienyl) carbonates and carbamates by treatment first with potassium terf-butoxide and then with a chloroformate or carbamyl chloride. In 1975, Oppolzer' reported the synthesis of tfans-N-(1