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Synthesis of 1,3,2-dioxathiolane-4-methylene-2-oxides: Potential allene oxide equivalents

✍ Scribed by Michael Shipman; Heidi R Thorpe; Ian R Clemens


Book ID
108379427
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
415 KB
Volume
55
Category
Article
ISSN
0040-4020

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Studies in ring-opening polymerization.
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## Abstract The polymerization of 5,5‐diethyl‐1,3,2‐dioxathiolan‐4‐one‐2‐oxide has been examined in various solvents at 60–100Β°C. Kinetic studies have shown that steric hindrance by the C~5~ ethyl substituents prevents the occurrence of a bimolecular propagation reaction involving direct attack by