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ChemInform Abstract: Synthesis of 1,3,2-Dioxathiolane-4-methylene-2-oxides: Potential Allene Oxide Equivalents.

โœ Scribed by Michael Shipman; Heidi R. Thorpe; Ian R. Clemens


Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Palladium-Catalyzed
โœ J.-E. BAECKVALL; C. JONASSON ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 29 KB ๐Ÿ‘ 1 views

Palladium-Catalyzed 1,2-Oxidation of Allenes. -Palladium-catalyzed oxidation of allenes (I) with p-benzoquinone in the presence of LiBr provides 1,2-dibromides in a regioselective fashion. A plausible reaction mechanism via (ฯ€-allyl)palladium intermediates is proposed. The very mild oxidation condit