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Synthesis of bridgehead-substituted bicyclo[2.2.1]heptanes by radical cyclization

โœ Scribed by Della, Ernest W.; Knill, Andrew M.; Pigou, Paul E.


Book ID
127247286
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
686 KB
Volume
58
Category
Article
ISSN
0022-3263

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## Abstract 4โ€Substituted bicyclo [2.2.2] octโ€1โ€yl radicals were generated by bromine atom abstraction from the corresponding 1โ€bromobicyclo [2.2.2] octanes and observed in solution by EPR spectroscopy. A tendency towards lower __a__(H~ฮฒ~) and __a__(H~ฮณ~) values for inductively electronโ€withdrawing