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Synthesis of 7-azabicyclo[2.2.1]heptane derivatives via bridgehead radicals

✍ Scribed by Alberto Avenoza; Jesús H Busto; Carlos Cativiela; Jesús M Peregrina

Book ID
108371486
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
105 KB
Volume
58
Category
Article
ISSN
0040-4020

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Synthesis of 7-azabicyclo[2.2.1]heptane
Synthesis of 7-azabicyclo[2.2.1]heptane derivatives by transformation of tropinone
✍ Elena Gómez-Sénchez; José Marco-Contelles 📂 Article 📅 2006 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 306 KB

## Abstract magnified image The bromination (CuBr~2~, AcOEt/CHCI~3~) plus Favorskii rearrangement (EtONa, EtOH) of __N__‐carbethoxytropinone (**4**), readily available from tropinone (**3**), affords mixtures of __exo__‐ and __endo__‐isomers of 2,7‐dicarbethoxy‐7‐azabicyclo[2.2.1]heptane (**1b**)