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N-Arylmethyl-7-azabicyclo[2.2.1]heptane derivatives: synthesis and reaction mechanisms

✍ Scribed by Elena Gómez; José Marco-Contelles; Elena Soriano; María L. Jimeno

Book ID: 108283112
Publisher: Elsevier Science
Year: 2009
Tongue: French
Weight: 434 KB
Volume: 65
Category: Article
ISSN: 0040-4020
DOI: 10.1016/j.tet.2009.09.013

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## Abstract magnified image The bromination (CuBr~2~, AcOEt/CHCI~3~) plus Favorskii rearrangement (EtONa, EtOH) of __N__‐carbethoxytropinone (**4**), readily available from tropinone (**3**), affords mixtures of __exo__‐ and __endo__‐isomers of 2,7‐dicarbethoxy‐7‐azabicyclo[2.2.1]heptane (**1b**)

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