Synthesis of branched 'nanotrees' by controlled seeding of multiple branching events
✍ Scribed by Dick, Kimberly A.; Deppert, Knut; Larsson, Magnus W.; Mårtensson, Thomas; Seifert, Werner; Wallenberg, L. Reine; Samuelson, Lars
- Book ID
- 109933458
- Publisher
- Nature Publishing Group
- Year
- 2004
- Tongue
- English
- Weight
- 342 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1476-1122
- DOI
- 10.1038/nmat1133
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📜 SIMILAR VOLUMES
We describe a remote glycosidation that allows us to form a branched trisaccharide in intramolecular fashion. The molecular design of the spacer molecule for the remote glycosidation was examined based on molecular mechanics calculations.
## Abstract An enzymatic tandem reaction is described in which the enzymes phosphorylase and __Deinococcus geothermalis__ glycogen branching enzyme (Dg GBE) catalyze the synthesis of branched polyglucans from glucose‐1‐phosphate (G‐1‐P). Phosphorylase consumes G‐1‐P and polymerizes linear amylose w