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Synthesis of a branched oligosaccharide by remote glycosidation

✍ Scribed by Haruo Yamada; Katsuaki Imamura; Takashi Takahashi

Book ID
104255965
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
233 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

We describe a remote glycosidation that allows us to form a branched trisaccharide in intramolecular fashion. The molecular design of the spacer molecule for the remote glycosidation was examined based on molecular mechanics calculations.

πŸ“œ SIMILAR VOLUMES

Synthesis of Oligosaccharide-Branched Ri
Synthesis of Oligosaccharide-Branched Ribofuranan by Ring-Opening Polymerization of a New Anhydroribo Trisaccharide Monomer
✍ Dai Yoshida; Shuqin Han; Kei-Ichi Narita; Kazuyuki Hattori; Takashi Yoshida πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 372 KB

## Abstract A new anhydroribotrisaccharide monomer, A2B3LR (**1**), was synthesized and ROP was carried out to elucidate the polymerizability and to obtain oligosaccharide‐branched polysaccharides with defined structures. The new trisaccharide monomer was found to be polymerized readily with BF~3~