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Synthesis of Bis(glycosylamino)alkanes and Bis(glycosylamino)arenes.

โœ Scribed by S. V. Metlitskikh; A. M. Koroteev; M. P. Koroteev; A. S. Shashkov; A. A. Korlyukov; M. Yu. Antipin; A. I. Stash; E. E. Nifantiev

Book ID
101998428
Publisher
John Wiley and Sons
Year
2006
Weight
16 KB
Volume
37
Category
Article
ISSN
0931-7597

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Synthesis of bis(glycosylamino)alkanes a
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โœ S. V. Metlitskikh; A. M. Koroteev; M. P. Koroteev; A. S. Shashkov; A. A. Korlyuk ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› Springer ๐ŸŒ English โš– 376 KB

The condensation of D mannose and D galactose with aliphatic and aromatic diamines afforded a series of bis(glycosylamino)alkanes and arenes. A possible mechanism was pro posed for the formation of 1,2 bis(ฮฒ D glycosylamino)benzenes.

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In connection with structural modification of the trehalase inhibitor trehazolin (1), as a new-type of glycohydrolase inhibitor, some glycosylamino-oxazolines were designed and synthesized. Among three oxazolines beta-galacto (3), beta-gluco (5) and alpha-manno-types (6) obtained in stable form, the