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Synthesis of bis(diethyldithiocarbamato)manganese(II) and tris(diethyldithiocarbamato)manganese(III)

โœ Scribed by Cassandra T. Eagle; Grant N. Holder; Amanda B. Goodman; Patrick E. Hicks; Katherine P. Shaber


Book ID
106241019
Publisher
Springer
Year
2001
Weight
178 KB
Volume
6
Category
Article
ISSN
1430-4171

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Bisยญ[tris(1,3-diยญaminoยญpropane)ยญmanganes
โœ Engelke, Lars ;Bensch, Wolfgang ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› International Union of Crystallography ๐ŸŒ English โš– 158 KB

Yellow crystals of [Mn(pn) 3 ] 2 [Sb 4 S 8 ]ร2H 2 O (pn = 1,2-diaminopropane) were synthesized under solvothermal conditions by reacting elemental Mn, Sb and S in an aqueous solution of 1,2diaminopropane. The structure is composed of cyclic [Sb 4 S 8 ] 4ร€ anions and octahedral [Mn(pn) 3 ] 2+ cations