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Synthesis and characterization of tris(diethyldithiocarbamato)osmium(III) and tetrakis(diethyldithiocarbamato)osmium(IV). Electrochemical behaviour of the tris complex

✍ Scribed by A.H. Dix; J.W. Diesveld; J.G.M. Van Der Linden


Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
151 KB
Volume
24
Category
Article
ISSN
0020-1693

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Heteroleptictris-complexes of osmium(III
✍ Bijan K. Roy; Tapan K. Mallick; Pradyut K. Das; Barindra K. Ghosh πŸ“‚ Article πŸ“… 1993 πŸ› Springer 🌐 English βš– 408 KB

A series of mixed-tris chelates of Os m and Os w of the general formula [OsDQz] ~ + [D = fl-ketoenolates (D1-D 3) or tropolonate (D4); Q = deprotonated 8-quinolinol] has been prepared and characterized by physico-chemical and spectroscopic methods. In MeCN solution the OsN20 ~ unit displays reversib