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Synthesis and Reactivity of New Mono- and Dinuclear Hydridoirida-β-diketones – The Formation and Characterization of a Dinuclear Tris-μ-acyliridium(III) Complex

✍ Scribed by Francisco Acha; María A. Garralda; Ricardo Hernández; Lourdes Ibarlucea; Elena Pinilla; M. Rosario Torres; Malkoa Zarandona


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
181 KB
Volume
2006
Category
Article
ISSN
1434-1948

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## Abstract The synthesis and crystal structures of three nonheme diiron(III) complexes with a tridentate N,N,O Schiff‐baseligand, 2‐({[2‐(dimethylamino)ethyl]imino}methyl)phenol (HL), are reported. Complexes [Fe~2~OL~2~(NCO)~2~] (1a) and [Fe~2~OL~2~(SAL)~2~]·H~2~O [SAL = __o__‐(CHO)C~6~H~4~O^–^] (