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Mixed-ligand complexes of osmium(III)/(IV) 8-quinolinolates: synthesis, characterization and redox behaviour

✍ Scribed by Bijan K. Roy; Sutapa Sinha; Barindra K. Ghosh


Publisher
Springer
Year
1994
Tongue
English
Weight
316 KB
Volume
19
Category
Article
ISSN
0340-4285

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πŸ“œ SIMILAR VOLUMES


Mixed-ligand complexes of osmium(III/IV)
✍ Pranab R. Basudhar; Sutapa Sinha; Pradyut K. Das; Barindra K. Ghosh πŸ“‚ Article πŸ“… 1996 πŸ› Springer 🌐 English βš– 391 KB

A group of mixed-tris chelates of type [OsAQ2 ] [A=isonitrosoacetophenonate (A ~) and isonitrosopropiophenonate (A2); Q = deprotonated 8-quinolinol (QI) and 2-methyl-8-quinolinol (Q2)] have been prepared by two distinct synthetic approaches. [OsAQ2] +, obtained by Ce Iv oxidation of [OsAQ2], can be

Heteroleptictris-complexes of osmium(III
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A series of mixed-tris chelates of Os m and Os w of the general formula [OsDQz] ~ + [D = fl-ketoenolates (D1-D 3) or tropolonate (D4); Q = deprotonated 8-quinolinol] has been prepared and characterized by physico-chemical and spectroscopic methods. In MeCN solution the OsN20 ~ unit displays reversib

Synthesis, Characterization and Redox Be
✍ Alexander M. Kirillov; Matti Haukka; M. FΓ‘tima C. Guedes da Silva; Armando J. L. πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 209 KB

## Abstract New mono‐ and dicarbonyl phosphane Re^I^ complexes [ReCl(L)~2~(CO)(PPh~3~)~2~] {L = 3,5‐Me~2~‐Hpz (3), quin (4)} and [Re(L)__~n~__(CO)~2~(PPh~3~)~2~][BPh~4~]__~m~__ {L = pz/Hpz, __n__ = 2, __m__ = 0 (2); L = 4,7‐Ph~2~‐phen, __n__ = 1, __m__ = 1 (5); L = 2‐Me‐dipic, __n__ = 1, __m__ = 0