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Synthesis of Bis[1,2]dithiolo[1,4]thiazines and a [1,2]Dithiolo[1,4]thiazine from Tertiary Diisopropylamines

✍ Scribed by Rees, Charles W.; White, Andrew J. P.; Williams, David J.; Rakitin, Oleg A.; Konstantinova, Lidia S.; Marcos, Carlos F.; Torroba, Tomás


Book ID
127393878
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
194 KB
Volume
64
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Bis[1,2]dithiolo[3,
✍ Carlos F. Marcos; Oleg A. Rakitin; Charles W. Rees; Tomas Torroba; Andrew J. P. 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

Bis [1,2]dithiolo [3,4-b][4',3'-e][1,4]thiazine-3,5-dione, a Planar 1,4-Thiazine. -Reaction of N-benzyldiisopropylamine (I) with S 2 Cl 2 gives N-benzyl-bisthiolothiazine (II) with typically folded structure. Debenzylation of (II) results in a dramatic flattening of the molecule structure giving th