Condensation of benzyl 2-acetamido-4,6-O-benzylidene-2-deoxy-a-D-galactopyranoside with 2,3,4-tri-o-acetyl-a-D-fucopyranosyl bromide in 1: 1 nitromethane-benzene, in the presence of powdered mercuric cyanide, afforded benzyl 2-acetamido-4,6-O-benzylidene-2-deoxy-3-0-(2,3,4-tri-O-acetyl-P-D-fucopyran
Synthesis of benzyl 2,3,4-tri-acetamido-2,3,4,6-tetradeoxy-α-d-galactopyranoside
✍ Scribed by S.Robert Sarfati; Ladislas Szabó
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 265 KB
- Volume
- 117
- Category
- Article
- ISSN
- 0008-6215
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📜 SIMILAR VOLUMES
In a continuing program for the synthesis of oligosaccharides that occur as part of mutinous glycoconjugates, we previously described\* the synthesis of the disaccharide methyl 3-0-(2-acetamido-2-deoxy-P-D-glucopyranosyl)-a-D-galactopyranoside (1). We have also demonstrated that 1 could be readily
## Abstract 1,4‐Anhydro‐2,3,6‐tri‐__O__‐benzyl‐α‐D‐glucopyranose **(1)** wird mit Triäthyloxonium‐tetra‐fluoroborat **(2)** zu einem linearen 2,3,6‐Tri‐__O__‐benzyl‐β(1 → 4)‐polysaccharid polymerisiert. Dies enthält einen geringen Teil α(1 → 4)‐Bindungen. Abspaltung der Benzylreste führt zum freien