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Synthesis of B-ring functionalised intermediates for the preparation of 1,9-dideoxy-forskolin derivatives

✍ Scribed by Béatrice M.F Lagnel; Aede de Groot; Christophe Morin


Book ID
104231377
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
109 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis


Advanced intermediates towards the preparation of 1,9-dideoxy-forskolin derivatives have been synthesised from larixol; in such derivatives, the B-ring -6 and -7 hydroxyl groups are of the required beta configuration.


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Synthesis of bicyclo[9.3.1]pentadecane d
✍ Federico Corelli; Donata Dei; Maria Menichincheri; James P. Snyder; Maurizio Bot 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 225 KB

The synthesis of regioisomeric bicyclo[9.3.1]pentadecane-3-one derivatives 1 and 2, interesting synthons for the preparation of novel diterpenoids, has been accomplished through an approach that entails as a key step the formation of a twelve-membered ring by an unprecedented intramolecular Dieckman