✦ LIBER ✦

Synthesis of, and NMR and CD studies on, methyl 4-O-[(R)- and (S)-1-carboxyethyl]-α-l-rhamnopyranoside and methyl 6-O-[(R)- and (S)-1-carboxyethyl]-α-d-galactopyranoside

✍ Scribed by Mats Andersson; Lennart Kenne; Roland Stenutz; Göran Widmalm

Book ID: 102998460
Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 487 KB
Volume: 254
Category: Article
ISSN: 0008-6215
DOI: 10.1016/0008-6215(94)84241-8

No coin nor oath required. For personal study only.

✦ Synopsis

The title compounds were prepared by condensation of a suitably protected monosaccharide and (RI-or W2chloropropanoic acid. Characterization by 'H and 13C NMR spectroscopy revealed minor chemical shift differences between the diastereomers. CD spectra showed differences between the (RIand (S)-l-carboxyethyl substituted monosaccharides, thereby facilitating determination of the absolute configuration of the substituent.

📜 SIMILAR VOLUMES

Conformational analysis of methyl 6-O-[(

Conformational analysis of methyl 6-O-[(R)- and (S)-1-carboxyethyl]-α-D-galactopyranoside by MM and Langevin dynamics simulations

✍ Roland Stenutz; Goran Widmalm 📂 Article 📅 1997 🏛 Springer US 🌐 English ⚖ 952 KB

ChemInform Abstract: Synthesis and NMR S

ChemInform Abstract: Synthesis and NMR Studies of Methyl 3-O-[(R)- and (S)-1-Carboxyethyl]-α-D-gluco-, galacto- and mannopyranosides.

✍ Lars Andersson; Lennart Kenne 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

ChemInform Abstract: Synthesis of Site-S

ChemInform Abstract: Synthesis of Site-Specific Deuterium Substituted Methyl 6-O-[(R)- and (S)-1-Carboxyethyl]-α-D-galactopyranoside and Conformational Analysis Thereof Based on J Couplings.

✍ R. STENUTZ; AA. PILOTTI; P.-E. JANSSON; G. WIDMALM 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

ChemInform Abstract: Lactones of Methyl

ChemInform Abstract: Lactones of Methyl 3-O-[(R)- and (S)-1-Carboxyethyl]-α-D-gluco-, Galacto-, and Manno-pyranosides.

✍ Lars Andersson; Lennart Kenne 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 27 KB 👁 1 views

The X-ray crystallographic structures of

The X-ray crystallographic structures of methyl 2-O-methyl-α-d-glucopyranoside and methyl 4,6-O-(S)-benzylidene-2-O-methyl-α-d-galactopyranoside

✍ Patrick McArdle; Desmond Cunningham; Elizabeth Lee; Margaret O'Gara 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 302 KB

As part of a programme involving X-ray crystallographic studies" of cis-and tpuns-fused hexopyranosides, we now report on the crystal structures of methyl 2-~-methyl-~-D-glucop~anoside\* (11, which was obtained by debe~lidenation of methyl 4,~-O-benzyIidene-2-O-methyI-3-O-~-tolylsulfonyl-~-~-glucopy

Synthesis of methyl 3-O-(2-O-methyl-α-l-

Synthesis of methyl 3-O-(2-O-methyl-α-l-fucopyranosyl)-α-l-rhamnopyranoside, methyl 3-O-α-l-rhamnopyranosyl-α-d-glucopyranoside, and methyl 3-O-[3-O-(2-O-methyl-α-l-fucopyranosyl)-α-l-rhamnopyranosyl]-α-l-rhamnopyranoside: di- and tri-saccharide segments of a lipo-oligosaccharide (LOS-1) of Mycobacterium szulgai

✍ Mukund K. Gurjar; Prathama S. Mainkar 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 489 KB