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Synthesis of and base-induced rearrangements in the 1,4-diazabicyclo[4.1.0]hept-4-ene system

✍ Scribed by Padwa, Albert; Gehrlein, Lane; Kinnel, Robin B.


Book ID
127280968
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
815 KB
Volume
40
Category
Article
ISSN
0022-3263

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Rearrangement of a Bicyclo[3.2.0]hept-2-
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## Abstract The chemistry of the highly substituted cyclobutanone derivative 2, which is easily accessible from 1, is dominated by the steric hindrance caused by the substitutents: Reduction with hydride reagents and nucleophilic additions with methyllithium are less stereoselective than correspond