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Synthesis of All Stereoisomers of Sulfinylcalix[4]arenes 1

โœ Scribed by Morohashi, Naoya; Katagiri, Hiroshi; Iki, Nobuhiko; Yamane, Yusuke; Kabuto, Chizuko; Hattori, Tetsutaro; Miyano, Sotaro


Book ID
120245206
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
225 KB
Volume
68
Category
Article
ISSN
0022-3263

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Synthesis of all possible stereoisomers
โœ D. Guillerm; M. Delarue; M. Jalali-Naini; P. Lemaรฎtre; J.-Y. Lallemand ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 162 KB

The three possible isomers of poLygodiaZ, epimers at C-9, cis and trans fused, are described. Controlled kinetic and thermodynamic epimerizations allow preparation of all stereoisomers from the same key intermediate.