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Synthesis of all possible stereoisomers of polygodial

✍ Scribed by D. Guillerm; M. Delarue; M. Jalali-Naini; P. Lemaître; J.-Y. Lallemand


Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
162 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis


The three possible isomers of poLygodiaZ, epimers at C-9, cis and trans fused, are described. Controlled kinetic and thermodynamic epimerizations allow preparation of all stereoisomers from the same key intermediate.


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