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Synthesis of a well-defined end-chain macrophotoinitiator of poly(ε − caprolactone) by combination of ring-opening polymerization and click chemistry

✍ Scribed by Mustafa Degirmenci,Pinar Atuk Besli,Nasrettin Genli

Book ID: 126358821
Publisher: Springer
Year: 2014
Tongue: English
Weight: 775 KB
Volume: 21
Category: Article
ISSN: 1022-9760
DOI: 10.1007/s10965-014-0540-2

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## Abstract A new well‐defined telechelic macrophotoinitiator of polystyrene was synthesized by combination of ATRP and click chemistry. The ATRP of styrene by means of 2‐oxo‐1,2‐diphenylethyl‐2‐bromopropanoate (PI‐Br) initiator with CuBr/2,2′‐bipyridine yields polystyrene with photoactive benzoin