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Combination of Ring-Opening Polymerization and “Click” Chemistry for the Synthesis of an Amphiphilic Tadpole-Shaped Poly(ε-Caprolactone) Grafted by PEO

✍ Scribed by Li, Haiying; Riva, Raphaël; Jérôme, Robert; Lecomte, Philippe


Book ID
120297906
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
232 KB
Volume
40
Category
Article
ISSN
0024-9297

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✍ Peichun Li; Zhean Xia; Amar Zerroukhi; Jianding Chen; Yvan Chalamet; Thomas Jean 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 403 KB 👁 1 views

## Abstract The kinetics and controllability of the Ti[OCH~2~CCl~3~]~4~‐initiated atom transfer radical polymerization (ATRP) of __n__‐butyl acrylate were investigated. Then, with Ti[OCH~2~CCl~3~]~4~ as the initiator, poly(ϵ‐caprolactone)‐__block__‐poly(__n__‐butyl acrylate) (PCL‐__b__‐PBA) copolym