Synthesis and characterization of mid-chain macrophotoinitiator of poly(ε-caprolactone) by combination of ROP and click chemistry
✍ Scribed by Degirmenci, Mustafa; Sarac, Mehmet Akif; Genli, Nasrettin
- Book ID
- 125344582
- Publisher
- Springer
- Year
- 2014
- Tongue
- English
- Weight
- 486 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0170-0839
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📜 SIMILAR VOLUMES
## Abstract A combination of ATRP and “click” chemistry is employed for efficient preparation of a novel well‐defined mid‐chain functional macrophotoinitiator of polystyrene. Bromo‐terminated polystyrene (PSt‐Br) is prepared by ATRP of styrene using a methyl‐2‐bromopropanoate initiator with CuBr/PM
## Abstract Maleimido‐terminated PCL (M‐PCL) and alkyne‐terminated PCL (A‐PCL) are prepared by the ring‐opening polymerization of __ε__‐caprolactone with __N__‐hydroxyethyl maleimide and 4‐pentyn‐1‐ol as initiators catalyzed by tin(II) trifluoromethane sulfonate at 25 °C, respectively. A series of