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Synthesis of a sterically congested diazirine: 2-azi-camphane

✍ Scribed by René Kupfer; Murray G. Rosenberg; Udo H. Brinker

Publisher: Elsevier Science
Year: 1996
Tongue: French
Weight: 134 KB
Volume: 37
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(96)01497-9

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✦ Synopsis

The synthesis of 2-azi-eamphane has been achieved despite the fact that the spiroeyelie carbon eente~ is sterically congested. Although the yield is somewhat low, the highly pure diazirine can be used as a precursor for the burgeoning class of sterically congested carbenes.

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