𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of a stable analogue of cytidine 5′-monophospho-3-deoxy-d-manno-2-octulosonic acid (CMP-KDO)

✍ Scribed by Martin Orbe; Alf Claesson

Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
531 KB
Volume
24
Category
Article
ISSN
0223-5234

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Synthesis of 3-deoxy-D-manno-2-octuloson
Synthesis of 3-deoxy-D-manno-2-octulosonic acid (KDO)
✍ Frick, Wendelin ;Krülle, Thomas ;Schmidt, Richard R. 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 423 KB

## Abstract [(Benzyloxy)(benzyloxycarbonyl)methyl]triphenylphosphonium bromide (8), obtained from glyoxylic acid via a convenient one‐pot procedure, reacted in a Wittig reaction with 4‐__O__‐benzyl‐2,3:5,6‐di‐__O__‐isopropylidene‐D‐mannose (7), readily synthesized on a large scale from D‐mannose, t

A Silicon-Mediated Synthesis of 3-Deoxy-
A Silicon-Mediated Synthesis of 3-Deoxy-D-manno-octulosonic Acid (KDO)
✍ Nico Bräuer; Andreas Kirschning; Ernst Schaumann 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 115 KB 👁 2 views

KDO (1) is synthesized in five steps, starting from 1,2-to the carbonate 9. Silicon-induced lactonization affords the lactone 10, which can be converted into NH 4 -KDO by anhydro-3,4:5,6-di-O-isopropylidene-D-mannitol ( 6). The epoxide 6, obtained from D-mannitol (2), reacts with lithiated standard