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Synthesis of a New Series of Chiral Tri- and Tetradentate Ligands and Their Application in Titanium-Catalyzed Pinacol Coupling Reaction.

✍ Scribed by A. Chatterjee; N. N. Joshi


Publisher
John Wiley and Sons
Year
2007
Weight
20 KB
Volume
38
Category
Article
ISSN
0931-7597

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## Abstract A new method for the __in situ__ generation of various Ti(III) complexes is presented. Cyclohexadienyl‐Ti(IV) derivatives, which are readily prepared from the corresponding lithiated cyclohexadienes, afford the corresponding Ti(III) complexes upon thermal Cο£ΏTi‐bond homolysis. The Ti(III