Development of New Chiral Phosphine-Salen Type Ligands and Their Application in the Cu(I)-Catalyzed Enantioselective Henry Reaction.
β Scribed by Jia-Jun Jiang; Min Shi
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 21 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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## Abstract In this study, 13 different chiral 1,3βdiamines were synthesized from (β)β__cis__β2βbenzamidocyclohexanecarboxylic acid. They were successfully applied as ligands in the Cuβcatalyzed asymmetric Henry reaction between benzaldehyde and nitromethane. It was confirmed that the enantioselect
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