Synthesis of 5-Ketopipecolic Acid from Glutamic Acid
β Scribed by FREED, MEIER E.; DAY, ALLAN R.
- Book ID
- 126126674
- Publisher
- American Chemical Society
- Year
- 1960
- Tongue
- English
- Weight
- 407 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
A stereo-and enantio-specific synthesis of the natural1 occurring cis-%hydroxy-(L)-pipecolic acid (3) is described, starting from Z-(L -glutamic the key step involves c chsation of a Y, to trans-%hydroxy-(L -pipecolic acl 3 3 rotected chlorohydrin, and also gives access acid, .
To determine to what extent methanol in addition to the commonly used glucose is an attractive alternative feedstock for glutamic acid production, a comparative theoretical consideration of possible yields is given. Methanol can be assimilated by bacteria via three different metabolic pathways. With