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Synthesis of 5-Azaindoles via a Cycloaddition Reaction between Nitriles and Donor−Acceptor Cyclopropanes

✍ Scribed by Moustafa, Mahmoud M. Abd Rabo; Pagenkopf, Brian L.

Book ID
118010158
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
429 KB
Volume
12
Category
Article
ISSN
1523-7060

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Highly Diastereoselective Synthesis of 1-Pyrrolines via SnCl 4 -Promoted [3 + 2] Cycloaddition Between Activated Donor-Acceptor Cyclopropanes and Nitriles. -The products are isolated as single cis diastereomers. Using standard imine chemistry, the preparation of useful derivatives such as (VI) is p