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Synthesis of 4-vinyl benzyl tetra-coordinate silicate monomer

✍ Scribed by Qinggang Kong; Xiaomo Zhang; Yiwu Quan; Qingmin Chen


Book ID
106001252
Publisher
Springer
Year
2007
Tongue
English
Weight
353 KB
Volume
59
Category
Article
ISSN
0170-0839

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The synthesis of the optically pure 1,4,5,6-tetra-O-benzyl-myo-inositols was achieved in four steps via diastereomeric 2,3-spire-acetals of myo-inositol with Land D-camphor as the key intermediates. Camphor dimethyl acetal was used for the acetalation reaction. The diastereomers were benzylated and