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Synthesis of 4-nitrophenylO-(2-acetamido-2-deoxy-β-d-glucopyranosyl)-(1 → 2)-O-(4-O-methyl-α-d-mannopyranosyl)-(1 → 6)-β-d-glucopyranoside. A potential specific acceptor-substrate forN-acetylglucosaminyltransferase-V (GnT V)

✍ Scribed by Shaheer H. Khan; Saeed A. Abbas; Khushi L. Matta

Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
983 KB
Volume
205
Category
Article
ISSN
0008-6215

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Halide-assisted glycosyIation, using a non-p~icipating Z-substituent (benzyl) in the glycosyl halide, was used to obtain the ~-D-gaiactosyl linkage and silver triflate promotion with a participating 2-substituent (benzoyl) was used to obtain the /3-D-galactosyl linkage in a facile synthesis of the t