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Synthesis of 2-acetamido-2-deoxy-β-d-glucopyranosyl-(1 → 2)-α-d-mannopyranosyl (1 → 6)-β-d-mannopyranosyl-(1 → 4)-2-acetamido-2-deoxy-d-glucopyranose. Acceptor-substrate recognition by N-acetylglucosaminyltransferase-V (GnT-V)

✍ Scribed by Shaheer H. Khan; Khushi L. Matta

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
626 KB
Volume
278
Category
Article
ISSN
0008-6215

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Treatment of benzyl 2-acetamido-2-deoxy-alpha-D-galactopyranoside with 4-methoxybenzaldehyde dimethyl acetal in N,N-dimethylformamide in the presence of 4-toluenesulfonic acid afforded the 4,6-O-(4-methoxybenzylidene) acetal, which was glycosylated with 2,3,4,6-tetra-O-acetyl-alpha-D-galactopyranosy