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Synthesis of 3-tert-butylcatechol by an engineered monooxygenase

✍ Scribed by Andreas Meyer; Martin Held; Andreas Schmid; Hans-Peter E. Kohler; Bernard Witholt


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
164 KB
Volume
81
Category
Article
ISSN
0006-3592

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Enantioselective synthesis of tert-butyl
✍ Stefano Colonna; Nicoletta Gaggero; Giacomo Carrea; Piero Pasta; Veronique Alpha πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 78 KB πŸ‘ 1 views

Cyclohexanone monooxygenase from Acinetobacter calcoaceticus catalyzes the asymmetric oxidation of tert-butyl disulfide to enantiomerically pure (R)-tert-butyl tert-butanethiosulfinate. Lower enantioselectivities and conversions were observed in the oxidation of i-propyl, n-butyl, p-tolyl tert-butyl