Enantioselective synthesis of tert-butyl
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Stefano Colonna; Nicoletta Gaggero; Giacomo Carrea; Piero Pasta; Veronique Alpha
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Article
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2000
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John Wiley and Sons
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English
β 78 KB
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Cyclohexanone monooxygenase from Acinetobacter calcoaceticus catalyzes the asymmetric oxidation of tert-butyl disulfide to enantiomerically pure (R)-tert-butyl tert-butanethiosulfinate. Lower enantioselectivities and conversions were observed in the oxidation of i-propyl, n-butyl, p-tolyl tert-butyl