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Enantioselective synthesis of tert-butyl tert-butanethiosulfinate catalyzed by cyclohexanone monooxygenase

✍ Scribed by Stefano Colonna; Nicoletta Gaggero; Giacomo Carrea; Piero Pasta; Veronique Alphand; Roland Furstoss

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 78 KB
Volume: 13
Category: Article
ISSN: 0899-0042
DOI: 10.1002/1520-636x(2001)13:1<40::aid-chir8>3.0.co;2-m

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✦ Synopsis

Cyclohexanone monooxygenase from Acinetobacter calcoaceticus catalyzes the asymmetric oxidation of tert-butyl disulfide to enantiomerically pure (R)-tert-butyl tert-butanethiosulfinate. Lower enantioselectivities and conversions were observed in the oxidation of i-propyl, n-butyl, p-tolyl tert-butyl disulfides and alkylthiophosphonates.

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