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Synthesis of 3-methylaspartic acids by ring-contraction of a nickelacycle derived from glutamic anhydride

✍ Scribed by Antonio M Echavarren; Ana M Castaño


Book ID
103404893
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
518 KB
Volume
51
Category
Article
ISSN
0040-4020

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Synthesis of protected 3-methylaspartic
✍ Ana M. Castaño; Antonio M. Echavarren 📂 Article 📅 1993 🏛 Elsevier Science 🌐 French ⚖ 168 KB

The syntbcais of fully protected fi-methyl sqartic acids kon~ (f)\_glutamic anhydride has been achieved by mems of ring contradoe of the derived nickelacycle followed by Moe of en isocyaide. Tbe intemdate five-manbaedringnickelacycleswereisulatedandcharsctcrized~~qlically.