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Nickelacyclic carboxylates derived from 3-hexyne and CO2 and their application in the synthesis of a new muconic acid derivative

✍ Scribed by Jens Langer; Helmar Görls; Dirk Walther


Book ID
113856573
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
765 KB
Volume
32
Category
Article
ISSN
0277-5387

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Synthesis of Chiral 1,3-Diamines Derived
✍ Dr. Koichi Kodama; Kazuyuki Sugawara; Prof. Takuji Hirose 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 438 KB 👁 1 views

## Abstract In this study, 13 different chiral 1,3‐diamines were synthesized from (−)‐__cis__‐2‐benzamidocyclohexanecarboxylic acid. They were successfully applied as ligands in the Cu‐catalyzed asymmetric Henry reaction between benzaldehyde and nitromethane. It was confirmed that the enantioselect