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Synthesis of 3-Aryl-1,3,5-pentanetricarboxylic acid trialkylestersviaa Tandem Addition-Rearrangement-Addition Reaction

✍ Scribed by Song Cao; Zheng Zhang; Ai-Long Fan; Zi-Ming Huang


Book ID
106213213
Publisher
Springer Vienna
Year
2003
Tongue
English
Weight
64 KB
Volume
134
Category
Article
ISSN
0026-9247

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pentanetricarboxylic Acid Trialkylesters via a Tandem Addition-Rearrangement-Addition Reaction. -It is noteworthy that in the reaction of (I) with various kinds of Michael acceptors, no regular mono-or double addition products are observed. A possible mechanism for the formation of (III) is given. -

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