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Synthesis of 3-Aryl-1,3,5-pentanetricarboxylic Acid Trialkylesters via a Tandem Addition-Rearrangement-Addition Reaction.

✍ Scribed by Song Cao; Zheng Zhang; Ai-Long Fan; Zi-Ming Huang

Publisher: John Wiley and Sons
Year: 2003
Weight: 104 KB
Volume: 34
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200333099

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✦ Synopsis

pentanetricarboxylic Acid Trialkylesters via a Tandem Addition-Rearrangement-Addition Reaction. -It is noteworthy that in the reaction of (I) with various kinds of Michael acceptors, no regular mono-or double addition products are observed. A possible mechanism for the formation of (III) is given. -(

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