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A New Addition—Rearrangement of [1,4]Thiazine-2-thiones with Aryl-1,2,4-triazoline-3,5-diones.

✍ Scribed by Nuria Garcia; Pedro Fuertes; Susana Barriga; Ana G. Neo; Daniel Miguel; Tomas Torroba


Publisher
John Wiley and Sons
Year
2003
Weight
75 KB
Volume
34
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Bis[1,2]dithiolo[3,
✍ Carlos F. Marcos; Oleg A. Rakitin; Charles W. Rees; Tomas Torroba; Andrew J. P. 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB

Bis [1,2]dithiolo [3,4-b][4',3'-e][1,4]thiazine-3,5-dione, a Planar 1,4-Thiazine. -Reaction of N-benzyldiisopropylamine (I) with S 2 Cl 2 gives N-benzyl-bisthiolothiazine (II) with typically folded structure. Debenzylation of (II) results in a dramatic flattening of the molecule structure giving th