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Synthesis of 3-alkyl-5-hydroxycyclohex-2-enones via aldolic addition/sulfinate elimination tandem reactions

✍ Scribed by Enrique Pandolfi; Horacio Comas

Book ID: 104253780
Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 133 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)01085-2

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✦ Synopsis

The first synthesis of 3-alkyl-5-hydroxycyclohex-2-enones is reported. An intramolecular cyclization by means of an aldolic addition/sulfinate elimination tandem reactions, performed under mild basic conditions was the key step.

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