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Tandem Michael Addition/Aldol Reaction of Allenic Ketones with Alkyl Vinyl Ketones: Versatile Synthesis of 2-Alkynyl 1,5-Diketones, 4-Alkynyl-3-hydroxycyclohexanones and 4-Alkynylcyclohexenones

✍ Scribed by Deepika Malhotra; Le-Ping Liu; Gerald B. Hammond

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
761 KB
Volume
2010
Category
Article
ISSN
1434-193X

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ChemInform Abstract: Tandem Michael Addi
ChemInform Abstract: Tandem Michael Addition/Aldol Reaction of Allenic Ketones with Alkyl Vinyl Ketones: Versatile Synthesis of 2-Alkynyl 1,5-Diketones, 4-Alkynyl-3-hydroxycyclohexanones and 4-Alkynylcyclohexenones.
✍ Deepika Malhotra; Le-Ping Liu; Gerald B. Hammond πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons βš– 38 KB πŸ‘ 2 views

## Abstract The reaction leads to the 2‐alkynyl‐1,5‐diketones (III), when catalyzed by Bu~4~NF in THF at room temperature.