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Synthesis of 2,5-Piperazinediones Having Sulfur-Containing Bridges between C3 and C6

✍ Scribed by Hans Poisel; Prof. Dr. Ulrich Schmidt


Publisher
John Wiley and Sons
Year
1971
Tongue
English
Weight
246 KB
Volume
10
Category
Article
ISSN
0044-8249

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Three selectively labeled propynes were prepared either with deuterium or carbon-13 at position 3 and doubly labeled with carbon-13 at positions 1 and 2 by an alkylation reaction from the corresponding labeled or unlabeled monolithio acetylides and dimethylsulfates. Their lithiation with nBuLi gave